Urban climate changes and the warming of the cities are serious issues that cannot be overlooked. One of the most common inferences for these changes is unprecedented and unplanned urbanization, which further causes a rise in local, regional, and even global temperatures. Although the rate of urbanisation defines and greatly influences the city's socioeconomic worth and GDP per capita, if the urban expansion is hap-hazardous, it can cause serious environmental harm.There has been a steep rise in global urban population over the past three decades, and the highest growth rates have been observed in Asian and African cities. These two continents have been predicted to contribute to almost 90% of the total urban growth from the present to 2050. India is one of the few highly susceptible countries to the harsh effects of climate change in terms of rise in temperatures. After 1990s', India has observed substantial changes in the landscape due to urbanization, which has led to a significant rise in the surface and ambient air temperatures, further affecting the planet's health. Elevated temperature drastically affects the health of urban dwellers leading to a rise in stress and discomfort levels. Estimation of Land Surface Temperature (LST) can play a vital role in understanding the region-specific alterations in temperatures as it uses satellite data that captures the entire region and provides the information in the form of pixels. Traditionally, the temperature was measured at meteorological stations and extrapolated for the entire region,whichinduces inaccuracies. This ambiguity can be amended by developing a relationship between LST and ambient air temperature. This communication focuses on LST estimation using Radiative Transfer Equation algorithm corresponding to various Landuse categories. The study also attempts to create a relationship between the LST and the ambient air temperature observed at two meteorological stations. An overall assessment of the number of days under stress for the residents was also performed over several years. Kolkata Metropolitan Area was considered the study area to represent the results and understand the complete analysis. A rise of 6.77 degrees C was observed in LST over the study period (2000-2019) due to an increment of 200% in the urban area. Analysis of the number of days under stress showed an increasing trend for the study area due to alterations in urban temperatures. These results and the suggestions from the scientific community, urban planners, and climate experts will help develop or modify the current policy frameworks for creating a balance between development and the environment, thus creating sustainable urban development.