Background: Sustained high temperatures, specifically heat waves (HW), increase the risk of dying, especially among risk populations, which are highly vulnerable to its additional effect. In developing countries, there are only a few studies which focused on the magnitude of the risks attributed to HWs. Objectives: This study explored the HW effects using 15 HW definitions through the combination of duration (> 2, > 4, and > 7 consecutive days) and intensity (at the >= 90th, >= 95th, >= 97th, >= 98th, and >= 99th temperature percentiles). Methods: Daily mortality count data from 2006-2010 were obtained from the four tropical cities of the Philippines, and were further stratified by mortality sub-groups, such as cause of death, sex, and age. The same period of daily maximum temperature and relative humidity were also collected. We used a distributed lag non-linear model to determine the risks associated with the main temperature effects, as well as the added HW effects. Results: It has been observed that the main temperature effects comprise a substantial portion of the risks compared to the HW effects, even across the mortality sub-groups. Further stratification by the sub-groups showed significant HW effects among the young and male populations. Conclusions: Results of this study can be of use to improve (1) candidate HW definition identification/ selection, and (2) risk population-specific strategies, taking into consideration the risk attributions.