The generation and emission of volatile organic compounds (VOCs) affects the environment and air quality, playing an important role in global warming, depletion of atmospheric ozone and emission of unpleasant odors, but also directly affect human health. This study investigated the health risks of benzene, toluene, ethylbenzene, xylene (BTEX) compounds and biogas released in and around the municipal landfill. Sampling of the VOCs was carried out by the 1501NIOSH method from 8 points over 5 months. The samples were analyzed for BTEX in the ambient air of the landfill, resulting in 0.03-18.09 ppm concentrations, while for biogases a 0.08-25.2 ppm range was found. Assessment of definite health and potential risks showed that the lifetime cancer risk (LCR) for benzene and hazard quotient (HQ) for the BTEX components in all studied sampling sites are higher than the acceptable standard. The high concentration of benzene measured in ambient air indicated that petroleum compounds containing benzene and its derivatives have the highest value in the category of BTEX compounds among all emissions. Therefore, high concentrations of volatile compounds derived from VOCs, especially benzene, should be reduced at the site with control engineering measures.